Product ID:PEP SET I 5110
MSDS Date:12/18/1987
FSC:6850
NIIN:00F015462
MSDS Number: BKDHP

ASHLAND CHEMICAL, INC.

COLUMBUS, OH 43216

Emergency Phone: (800) 274-5263

Info Phone: (614) 889-3333

Cage: 5A188

ASHLAND CHEMICAL CO

DUBLIN, OH 43017 US

Telephone: 614-889-4505

Cage: 5A188

SOLVENT NAPHTHA, PETROLEUM, LIGHT AROMATIC C8-C10 (AROMATIC

CAS: 64742-95-6

Fraction By Weight: 63%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 4-41%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CUMENE (SARA III)

CAS: 98-82-8

RTECS: GR8575000

Fraction By Weight: 1-89%

OSHA PEL S, 50 PPM

ACGIH TLV: S, 50 PPM; 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

TRIMETHYL BENZENE (SARA III)

CAS: 25551-13-7

RTECS: DC3220000

Fraction By Weight: 25.2%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9192

1,2,4-TRIMETHYLBENZENE (SARA III)

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: 12.6%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9192

1,3,5,-TRIMETHYLBENZENE

CAS: 108-67-8

RTECS: OX6825000

Fraction By Weight: 2.67%

ACGIH TLV: 25 PPM

AMINE POLYOL

Fraction By Weight: 30-60%

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SKIN: IRRITATION, DEFATTING, &
DERMATITIS. EYE: IRRITATION, REDNESS, TEARING, & BLURRED VISION.
INHALATION: NASAL & RESPIRATORY IRRITATION, CENTRAL NERVOUS SYSTEM
EFFECTS, DIZZINESS, WEAKNESS, FATIGUE , NAUSEA, HEADACHE,
UNCONSCIOUSNESS, & DEATH. INGESTION: GASTROINTESTINAL IRRITATION,
NAUSEA, VOMITING, & DIARRHEA.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:SKIN: IRRITATION, DEFATTING, & DERMATITIS. EYE:
IRRITATION, REDNESS, TEARING, & BLURRED VISION. INHALATION: NASAL &
RESPIRATORY IRRITATION, CENTRAL NERVOUS SYSTEM EFFECTS, DIZZINESS,
WEAKNESS, FATIGUE , NAUSEA, HEADACHE, UNCONSCIOUSNESS, & DEATH.
INGESTION: ASPIRATION INTO LUNGS MAY CAUSE CHEMICAL PNEUMONITIS &
FATAL.

First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. SKIN:
WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. GIVE CPR OR
OXYGEN IF NEEDED. KEEP WARM & QUIET. INGESTION: DON'T INDUCE
VOMITING. KEEP PERSON WARM & QUIET. OBTAIN MEDICAL ATTENTION IN
ALL CASES.

Flash Point Method:SCC
Flash Point:118F
Lower Limits:1%
Upper Limits:7%
Extinguishing Media:REGULAR FOAM, WATER FOG, CO2, & DRY CHEMICAL.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS W/FULL
FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE.
Unusual Fire/Explosion Hazard:VAPORS ARE >AIR & TRAVEL ALONG THE
GROUND/MOVE BY VENTILATION & IGNITE BY HEAT, PILOT LIGHTS, FLAMES,
IGNITION SOURCES AT AREAS DISTANT FROM HANDLING POINT.

Spill Release Procedures:ELIMINATE SOURCES OF IGNITION. ABSORB ON
PAPER/VERMICULITE/FLOOR ABSORBENT & TRANSFER TO HOOD. EVACUATE
AREA. STOP AT SOURCE. DIKE AREA TO PREVENT SPREADING, PUMP LIQUID
TO SALVAGE TANK. REMAINING LIQ UID TAKE UP ON SAND/CLAY/EARTH &
SHOVELIN DRUM.

Handling and Storage Precautions:CONTAINERS OF THIS MATERIAL MAY BE
HAZARDOUS WHEN EMPTIED DUE TO PRODUCT RESIDUES. USE PRECAUTION
DURING POURING, COOLING/SHAKEOUT. AVOID SKIN CONTACT
Other Precautions:NEVER USE WELDING/CUTTING TORCH ON/NEAR DRUM (EVEN
EMPTY) BECAUSE PRODUCT (EVEN JUST RESIDUE) CAN IGNITE EXPLOSIVELY.
ALL 5 GALLON PAILS & LARGER METAL CONTAINERS, TANK CARS/TRUCKS
SHOULD BE GROUNDED/ BONDED WHEN TRANSFERRED.

Respiratory Protection:IF >TLV, USE A NIOSH/MSHA APPROVED AIR SUPPLIED
RESPIRATOR. ENGINEERING OR ADMINISTRATIVE CONTROLS SHOULD BE
IMPLEMENTED TO REDUCE EXPOSURE. OSHA PERMITS NIOSH/MSHA RESPIRATOR
(NEGATIVE PRESSURE TYPE) UNDER SPECIFIED CONDITIONS.
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL &/OR LOCAL EXHAUST)
VENTILATION TO KEEP Protective Gloves:CHEMICAL RESISTANT, NITRILE RUBBER
Eye Protection:CHEMICAL SPLASH GOGGLES, SAFETY GLASSES
Other Protective Equipment:IMPERVIOUS CLOTHING & BOOTS.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. REMOVE CONTAMINATED SHOES & DISCARD.
Supplemental Safety and Health
THIS PRODUCT IS A COMPONENT OF A FOUNDRY BINDER SYSTEM (CASTING
METALS). "ITEM COMPOSITION IS IN PERCENT BY VOLUME."

Boiling Pt:B.P. Text:308F
Vapor Pres:3
Vapor Density:>AIR
Spec Gravity:Evaporation Rate & Reference:SLOWER THAN ETHER
Percent Volatiles by Volume:60-65%

Stability Indicator/Materials to Avoid:YES
STRONG ALKALIES, MINERAL ACIDS, & OXIDIZING AGENTS.
Stability Condition to Avoid:SOURCES OF IGNITION, FLARES, PILOT LIGHTS,
ELECTRICAL SPARKS, HEAT, & FLAMES.
Hazardous Decomposition Products:CO2, CO, NITROGEN COMPOUNDS, VARIOUS
HYDROCARBONS, ALDEHYDES, PHENOLS, OXYGENATED COMPOUNDS,
ISOCYANATES, PARTICULATES.

Waste Disposal Methods:ALLOW VOLATILE PORTION TO EVAPORATE IN HOOD &
TIME FOR VAPORS TO CLEAR HOOD DUCT WORK. LARGE SPILL DESTROY BY
LIQUID INCINERATION, DEPOSIT CONTAMINATED ABSORBENT IN LANDFILL,
ALL IN ACCORDANCE W/LOCAL , STATE, & FEDERAL REGULATIONS.
COMBUSTIBLE LIQUID

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.